A lot of novel phenomena have been found at interfaces of two different materials such as 2D electron gas at LaAlO3/SrTiO3. Observation of density of states provides a direct evidence for these phenomena. I used scanning tunneling microscopy (STM) to probe the electron properties at the interface of cuprate superconductor YBa2Cu3O7-x and multiferroics BiFeO3 with different domains. The STM images and spectrum revealed the polarization effect on superconductivity.